Transition metals reactivity2/29/2024 ![]() ![]() ![]() Looking for something specific in this course? The Resource Index compiles links to most course resources in a single page. Lecture 29: Transition Metals: Crystal Field Theory Part II Lecture 28: Transition Metals: Crystal Field Theory Part I Lecture 27: Introduction to Transition Metals Lecture 26: Chemical and Biological Oxidations Lecture 25: Oxidation-Reduction and Electrochemical Cells By the end of the unit, viewers should be able to calculate electrochemical cell potentials, identity which compound is the better oxidizing agent, draw energy diagrams that explain why one cobalt compound is blue and another red, and explain how a chelator works to treat acute lead poisoning. Viewers can observe some of these special properties for themselves as spectacular color changes afforded by solutions of nickel and cobalt salts are demonstrated. Revisiting the concept of atomic orbitals, we discuss how the occupation of electrons in d-orbitals gives rise to the special properties of d-block metal-containing complexes. Whereas metals in group I and II of the periodic table are only oxidized by one and two electrons, respectively, transition (d-block) metals are capable of achieving multiple oxidation states. For example, the most stable compounds of chromium are those of Cr(III), but the corresponding Mo(III) and W(III) compounds are highly reactive. In Unit IV, we continue to consider chemical reactions but now focus on reactions that involve the loss (oxidation) and gain (reduction) of electrons. For example, the HgC bond of (MeHg) + cation is indefinitely stable in aqueous H 2 SO 4 solution in air. On the contrary the late transition metal organometallic compounds are much less reactive and stable. This Special Issue is devoted to all aspects of transition metal chemistry. It is closely related to other fields such as supramolecular chemistry, photochemistry, catalysis, medicine, materials science, quantum chemistry, etc. Despite their long history in catalysis, the discovery of new. Some of the early transition metal catalyzed reactions are still being used today. Finally, we extend our analysis to ternary transition-metal alloys and identify the most resilient compounds to O and S binding.Unit IV: Transition Metals & Oxidation-Reduction Reactions Similar high reactivity was also observed in case of the early transition metal organometallic compounds particularly of Ti and Zr. The coordination chemistry of transition metals is one of the most important and extensive areas of modern chemistry. Transition metals make excellent catalysts as they have incompletely filled d-orbitals that allow them to both donate and accept electrons easily from other molecules. Such descriptor is then applied to a vast database of electronic structures of transition-metal alloys, for which we are able to predict the range of binding energies across both the compositional and the structural space. This is here obtained by fitting several schemes, based on the original Newns-Anderson model, against density-functional-theory data for the 4$d$ transition metal series. The analysis is performed by defining a suitable descriptor for the binding energy. With this in mind, we present a systematic study of the binding energy of O and S across the entire transition-metals composition space, namely we explore the binding energy of transition-metal binary alloys. These are always initiated with O and S binding to a metallic surface, so that one can use the binding energy as a rough proxy for the metal reactivity. Download a PDF of the paper titled Reactivity of transition-metal alloys to oxygen and sulphur, by Rajarshi Tiwari and 2 other authors Download PDF Abstract:Oxidation and tarnishing are the two most common initial steps in the corrosive process of metals at ambient conditions.
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Best id3 editor2/29/2024 ![]() If you have a large music collection, you can use it to automatically create tags based on file names or folder names. It allows batch tag editing for ID3v1, ID3v2.3, ID3v2.4, iTunes MP4, WMA, Vorbis Comments, and APE Tags, and it supports a range of audio formats. Even if you've never changed MP3 tags before, you won't have trouble working out what to do because it's simple to use. Without downloading any software or installing any extensions, TagMP3 allows you to rapidly edit the song title, artist name, album name, album art, and other information. With the help of TagMP3, an online MP3 tag editor, you can quickly modify the metadata of your MP3 files from any web browser. ![]() You can also add your own artwork to set it as media cover. Then you can edit your MP3 tags like output name, song name, artist, album, genre, comment, lyrics, etc. You can also drag and drop your music files here.Then click the Codec Option button to continue. Click +Music to upload your MP3 audio from computer. On your Windows or Mac computer, launch VideoProc Converter AI and select the Video option. These AI features are not yet available in the Mac version but will be coming soon. Note: The Windows version now supports AI-powered Super Resolution, Frame Interpolation, and Stabilization to enhance video and image quality. Additionally, it allows you to combine multiple audio files into a single file, making it super easy to manage your music library. If you want to convert a video file to an MP3 or other audio format, this can be useful. Its powerful audio processing engine makes sure that even after editing, your audio recordings keep the original sound quality.Īnother awesome feature of VideoProc Converter AI is extracting audio out of video files. It allows you to cut and trim audio files, change the volume, add effects, and even convert to various audio formats. VideoProc Converter AI provides a number of advanced audio editing features besides basic MP3 tag editing. You can quickly change the music title, artist name, album name, album art, genre, comment, and other MP3 file metadata with VideoProc Converter AI. Editing MP3 tags is one of its less well-known functions. VideoProc Converter AI is an all-in-one video and audio processing program equipped with a lot of useful features. Best MP3 Tag Editor for Win/Mac - VideoProc Converter AI Let's get started with our selection of the top MP3 tag editors for Windows and Mac without further ado. These tools will help you keep your music library organized and make it easy to use, whether you're a professional DJ or simply a casual music listener. ![]() You can edit the song title, artist name, album name, album art, and other metadata of your audio files using some MP3 tag editors.īased on their functionality, compatibility, and features, we will look at the top 5 MP3 tag editors for Windows and Mac in this article. ![]() Incorrect metadata can make it difficult to sort and filter your audio as well as to locate the songs you want to listen to. However, maintaining order in our music libraries is a task that comes along with this convenience.ĭealing with incorrectly labeled or missing metadata is one of the most annoying aspects of managing a music collection. We now have almost limitless audio available to us thanks to the development of digital music. We listen to it while we study, fitness, and relax. Music plays a crucial role in our daily life. Miss raindrop twerking2/29/2024 For four consecutive tournaments from January until July 2014, although still injured, he fought (and won) one match at the end of the tournament, solely to prevent falling off the banzuke completely. This resulted in him falling all the way down to jonokuchi 17 in the rankings. During his long injury recuperation he made two abortive attempts to return, breaking the hip twice more. However Ryuden suffered a fracture of his right hip joint in his juryo debut in November and had to withdraw from the tournament. He was also the first sekitori from Yamanashi Prefecture since Hidenohana 24 years earlier. He was the first sekitori produced by the new Takadagawa head Akinoshima, who had taken over the running of the stable from former ozeki Maenoyama in 2009. However after scoring a perfect 7–0 record and taking the makushita championship, Ryuden eventually reached the juryo division himself after the September 2012 tournament. He was overtaken by Takayasu who did become the first Heisei born sekitori in November 2010, with Masunoyama. However his progress then stalled with two consecutive make-koshi, and he suffered a concussion after falling from the dohyo in a match against Takanoiwa in March 2010, and was embarrassed when he had to be carried off in a wheelchair. He was talked of, alongside Masunoyama, as a candidate for the first wrestler born in the Heisei era to reach the sekitori ranks when he produced a 5–2 score at the rank of makushita 15 in November 2009. In July 2009, Ryuden produced a 6-1 record and was placed in an eight-man playoff for the makushita yusho, however he lost to Sotairyu in the first round. He bounced back and forth between makushita and sandanme for a couple of months, before becoming a makushita regular beginning from November 2008. ![]() Ryuden gradually rose the ranks through the lower divisions and reached the makushita division in March 2008 at the young age of 17. He was immediately given the shikona of Ryuden, with the "Ryu" part taken from his hometown school and the "den" part from the legendary wrestler Raiden. He made his debut in March 2006, the same tournament as Tochinoshin, Sakaizawa and Masakaze. ![]() However, he was persuaded by the former sekiwake Akinoshima, a coach at Takadagawa stable who was visiting his junior high school to scout a judo classmate, to give sumo a try. Watanabe was the youngest of three brothers and had a background in judo. Best peeler for potato chips2/29/2024 ![]() Ī Chef’s Knife- This option will give you a little thicker potato chip.īenriner BR1 VEGETABLE SLICER, One Size, Off-White GANNK Potato Peelers for Kitchen, Vegetable Peeler Julienne Peeler 3 in 1, Make Veggie Salad, Y and I Shape Apple Fruit Carrot Zucchini Veggie Peeler Santoku Knife – 7 Inch 67 Layer VG10 Damascus Steel Japanese Chef Knife, Sushi, Kitchen Knife, Japanese Kitchen Knives – Damascus Knife, Chopping Knife, Sushi Knife, Sharp Knife, Full Tang Knife Mercer Culinary M20003 Genesis 3. Vegetable Peeler- This option will give you the potato shape that most resembles those you’ll get from a mandoline. This is a great time to break out your mandoline slicer or use a very sharp chef’s knife. Slice the potatoes very thinly (about 1/8 inch thick) and uniformly so they cook evenly. Russet potatoes are usually flavored with butter and salt. Each one will create a different type of flavor, and you may want to augment that flavor with spices like a chipotle spice or packet of Ranch Dressing. Season with salt & pepper when they come out of the oven.Ī baking potato is the most common potato used for making potato chips, but you can use other potatoes as well. Season lightly with salt and arrange them in a single layer on a prepared baking sheet with parchment paper. Slice the potatoes into a bowl and immediately toss them with olive oil. The exact time will vary depending on the wattage of your microwave.Microwave for 5 minutes, or until they become crispy.Place the potato slices on the parchment lined plate in a single layer.Cut a piece of parchment paper to fit the microwave-safe plate.To achieve the best result a knife peeler can be placed behind an abrasive peeler and used to smooth the. ![]() Share: Potato-peeling is an active and crucial stage of production and can have a decided effect on the quality and. Place them in a bowl and add the olive oil. Lay’s Unveils 60+ New Potato Chip Bags for Smiles.Use a mandoline on the thinnest setting to slice the potato into thin chips.Coarse Salt – Without a pinch of salt, the flavor might be a little too flat.Olive Oil – Adds depth to the flavor of your chips.Potatoes – You can’t have chips without potatoes.What Do I Need To Make Microwave Potato Chips? However, please know that I only provide links to products that I actually use and wholeheartedly recommend! I am a member of amazon services llc associates program. *This site contains affiliate links which means that I may receive commissions for purchases made through these links. Aquarium tour virtual2/29/2024 Enter the different buildings-from the opulent mansion to the chilling slave quarters-and click on different items for video and text explanations. This virtual experience of George Washington’s home is incredibly well done. The website offers five different webcams featuring areas such as the tavern and the armory. This living-history museum provides a look into life in an early American community. The four featured music locations are: Vienna, Austria New Orleans, Louisiana Cleveland, Ohio and Bristol, Tennessee-Virginia. Birthplace of Musicīoise State put together this fully interactive virtual field trip with text, photos, audio, and video about the history of music. The star of the show is the behind-the-scenes tour of the Johnson Space Center. The “Museum of We the People,” the Constitution Center serves as a “headquarters for civic education.” Check out the Interactive Constitution section, and be sure to watch the virtual tour. If you enter your location, you can see all the constellations that are visible in the night sky in your corner of the world. Through Stellarium Web, kids can explore over 60,000 stars, locate planets, and watch sunrises and solar eclipses. Check out everything the National Park Service has to offer virtually. The interactive maps are a great way to see the Mammoth Hot Springs and Mud Volcano, but we think kids will be psyched about the Old Faithful Geyser livestream and the opportunity to make their own predictions for its next eruption. Our top pick would have to be Yellowstone. A National Parkįrom webcams at Hawaii volcanoes to a virtual run along the rim of the Grand Canyon, you have tons of options here. Check out the current virtual tours: Traveling Materials and Objects, the Advent of the Artist, the Body in Movement, and Founding Myths: From Hercules to Darth Vader! 6. And you can’t miss the world-famous Louvre in Paris (no passport needed!). We found 20 art museums with virtual tours, including the Metropolitan Museum of Art’s # MetKids and its awesome Where’s Waldo? setup. We’re also loving these virtual egg farm field trips from the American Egg Board. Farm Food 360 gives students the opportunity to immerse themselves in Canadian farm and food tours-from raising pigs to making milk and cheese. The classic preschool field trip goes online! You can have your pick of dairy farm field trips, but we like this one from the Dairy Alliance and this one from Stonyfield Organic. Space Innovation Tour: Students will learn about the amazing technology on board the Orion spacecraft in NASA’s Artemis I flight test and hear from the engineers who made it all possible.(New!) Data Center Tour 2: Keeping Data Safe and Sustainable: Discover the infrastructure that keeps your information safe and sustainable while diving into data careers of the future.(New!) Data Center Tour 1: Uncovering Cloud Computing: Do students know what “the cloud” actually is? Find out how we went from renting movies at the store to streaming them from anywhere at any time.Amazon Fulfillment Center Tour: Explore how packages get delivered at lightning speed and how computer science, engineering, and real people work together to make the magic happen.Tour whenever, wherever on Kahoot! Each tour comes with a Teacher Toolkit that includes a facilitation guide and student worksheets. Amazon Career Tours AmazonĪmazon Career Tours are free virtual field trips that inspire students to pursue careers of the future. Just click the CC button in the bottom right-hand corner.) 1. (Note: For anyone who needs it, YouTube offers a closed-captioning option. No fundraising or permission slips required! Not only do they fill in for real field trips when budgets and other roadblocks prevent in-person options, but virtual field trips also open doors to educational experiences all over the country and the world, both past and present. *This method will charge tax.Virtual field trips are a game changer. Students who participate in this virtual field trip will learn to evaluate the importance of different ocean habitats and understand connections between living and nonliving parts of an ecosystem. We even take a deep dive into the midnight zone to learn how animals of the deep sea have evolved to cope with extreme temperatures, pressures, and darkness. ![]() We alos explore the important ecological connections between these habitats and the animals that reside in them. Into the EcoZone gives students an exciting look at teh biodiversity of our ocean through an exploration of habitats featured in the Oklahoma Aquarium's EcoZone gallery, which features many habitats that serve as nurseries for our oceans- like coral reefs, rocky coasts, tide pools, kelp forests, and marshes. Dia de los muertos makeup half face2/29/2024 ![]() On November 2nd, families and communities across Mexico and parts of Latin America unite to pay homage to their dearly departed. That's also why Merson created three new Reina Rebelde products - a 4 Play Wet Dry Eye Color in Azteca ($23), On Your Face Contour + Color Trio in Coqueta ($23), and Lip Brilliance color in Bomba ($17) - in honor of the holiday: to celebrate all things beautiful about the tradition. MAKEUP 6 Stunning and Symbolic Da de los Muertos Makeup Looks Unveiled Da de los Muertos (or Day of the Dead) is a cherished Mexican tradition full of artistry and remembrance. Instead, sugar skull makeup has a place when done with the right intentions, and with respect and understanding of its significance. That Catrina represents your dead relative, not a comic book character." "One of the most offensive things is when people paint a Catrina and make the look intersect with something scary and bloody. "It is not a holiday about fantasy or horror, but rather something that is meant to be soulful and uplifting and positive," says Merson. The biggest point of contention, adds Regina Merson, Mexican-American beauty entrepreneur and founder of Reina Rebelde, is the many points of differentiation between Día de los Muertos and any other holiday where dressing in costume is ritualized, like Halloween. Want to learn how to create a sugar skull style face-painting design for kids just in time for Dia de los Muertos, or Day of the Dead Hope you like this tut. It depends on the way you see it and also how people carry a tradition that's not originally theirs." Half sugar skull day of the sugar skull day of the dead makeup 23 best day of the dead makeup ideas día de los muertos makeup ideas for. See more ideas about sugar skull makeup, dead makeup, skull makeup. 1 and goes into the early morning of Nov. These skulls are molded out of sugar and adorned in colorful beads, foils. One element of Dia de los Muertos is a calavera de azucar, which is growing in popularity. We see death as the beginning of another life, so there is a very fine line between appropriation and appreciation. Explore Dia de los Muertos Festival - s board 'Dia de los Muertos Makeup', followed by 633 people on Pinterest. Dia de los Muertos (Day of the Dead in Spanish) is celebrated at the eve of October 31 st, and then continues on to November 1 st and 2 nd. "Día de los Muertos is more than just painting your face with the shape of a sugar skull we are honoring our loved ones that have left this earth. Flowers and sugar skull designs are part of the dress. ![]() Its feminine and a bit flirty, with a form-fitting bust, fitted waist, and poofy, short skirt. It comes with a dress, a mask, and an oversized scarf. The Adult Exuberante Day of the Dead Costume is available in plus sizes, ranging from small to 3X. "As a makeup artist, I've seen the sugar skull makeup trend blow up and fall in the line of appropriation, but I also love seeing people expressing their art and representing my culture," Mexican-American makeup artist Valeria Leyva tells POPSUGAR. Adult Exuberante Day of the Dead Costume. Highland lynx kittens adopt alabama2/28/2024 ![]() ![]() Love Lynx is a small cattery + kitty boutique devoted to changing families' lives by adding a colorful 'kitten'-ality into the mix, completing your home with a silly little, purring companion. My husband will not let me be a crazy cat lady, because, all know I probably would be if it weren't for him, so we settled on the opportunity to grow the Highland Lynx cat breed which means I get all the fun with kittens but, at the end of 8 weeks they get to go home to amazing families, like yours, that happen to be cat lovers like myself. And, after doing thorough research to determine if this was the breed for us, we ultimately decided to pull the trigger. The 'unknown' of what happened was just not something I wanted to endure again so my husband and I began looking into other kitty options which ultimately led to learning about different purebred exotic cats, including a Highland Lynx. Shortly after, I took in a stray outdoor cat whom loved to be outdoors naturally but within the year after taking her in, she disappeared. ![]() How did I come across the Highland Lynx cat breed you ask? It came from a 'low-point' of my life when I had to put down my 'first' cat suddenly. Taking care of animals is therapeutic to me and so fun plus I now get to include my daughter in all of the fun and cuteness, too! Fast forward to today- two cats, two dogs, two goats, two ducks, a fuzzy husband, a one year old daughter later I've built quite the animal abode, starting with a foundation of cats! I'm a cat lover at heart and an animal lover by nature. As I grew, cats would come and go but each of them had a distinct personality and took a little piece of my heart. there has been many occasions of taking in a stray cat. Bringing home a new cat or kitten brought so much excitement to me as a kid, and I'm not talking buying or adopting. Since I can recall, I've always had a cat companion. E license cubase2/28/2024 Download the latest installer for Mac OS X and Windows at. Simply install the eLCC separately on the Internet computer without installing the complete product. In case you have no connection to the Internet on the computer on which you wish to use the USB-eLicenser, you can always use a different computer for activation. ![]() To activate other licenses, simply repeat the steps listed above. After completion of the activation procedure the new license is displayed in the eLicensers list and your product is ready for use.For further information on this subject, refer to the Help section in the eLCC. Most products including Cubase, Dorico, Nuendo, WaveLab, SpectraLayers and Groove Agent transitioned to the new licensing system. Here is an overview of all Help Center articles related to Steinberg Licensing and the transition from the eLicencer-based licensing. Two months later, on January 12, 2022, Dorico 4, the first product using Steinberg Licensing, has been released. To do this, enter the required activation code into the corresponding field. In November 2021, we announced Steinberg Licensing, a new user-friendly licensing technology. Click the "Enter Activation Code" button to download the license for your Steinberg product to the USB-eLicenser.In this case, the "eLicensers" list should display at least one USB-eLicenser. ![]() Important: Activation of the license requires that at least one USB-eLicenser is connected to a USB port on your computer and that it is identified by the operating system. ![]()
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